The Redox Potential in Aquariums (And Ponds) And How it Relates to Proper Aquatic Health

This article is based on a study about the Redoxfrom a mass of water) are oxidized to the
Potential as it corresponds to humans and all fishhydrophilic forms (a molecule or portion of a
and animals. Although not a well known processmolecule is one that is typically charge-polarized
among many aquarists, the implications of Redoxand capable of hydrogen bonding, enabling it to
for a healthy aquarium are quite far reaching, anddissolve more readily in water than in oil or other
thus important for any aquarist consideringhydrophobic solvents), which are characterized by
moving from basic aquarium (or pond) keeping tothe better biological compatibility. Energy of
advanced to understand.oxidation of degrading organic compounds is
Redox, also known as Redox Potential, oxidationabsorbed during reduction chemical
potential, & ORP (oxidation reductiontransformations. Excess of ions of the heavy
potential) describes the ability for the loss of anelements transforms into insoluble, inert, nontoxic
electron by a molecule, atom or ion to the gain offorms. Concentration of ions of light elements is
an electron by another molecule, atom or ion.stabilized. Just in such water live the water
Without this ability to gain electrons many mineralsorganisms, and land animals drink such water.
cannot be absorbed and properly assimilated. So itSpring waters, which are considered to be the
is very important to keep a healthy Redoxmost clean according to the ecological criteria, are
Balance via proper dissolved oxygen levels, UVfiltered through the rocks and subjected to the
Sterilization, and proper positively charged mineraloxidation and reduction, sorption and catalytic
levels (such as Calcium and Magnesium). A properinfluence. As rule, they are mineralized and include
Redox Potential improves the health of humansnon-volatile organic substances, which are
AND fish. A Redox Potential in the -200 to -400detected by the permanganate oxidability
mV range in human studies has been shown to(expressed by oxidability by potassium
have the same affect as anti-oxidant preparationspermanganate and potassium dichromate).
such Vitamin C (and many others).After electrochemical purification water keeps its
A UV Sterilizer can help balance the normalinitial neutral values of pH, but ORP (Oxidation
oxidizing processes by adding electrons, as moreReduction Potential) of water shifts toward the
and more current research in human studies isnegative (electrode or reduction) values. The
bearing out. This shows that the health ofresulting purified water obtains the antioxidant
aquarium fish can be maintained by a UV Sterilizerproperties with characteristics of pharmacological
not just by the killing of potential diseaseactivity close to the properties of the antioxidant
pathogens, but by the maintenance of a properpreparations (a -tocopherol, b -carotene, vitamin C
Redox Potential. I have been observing manyetc.). In case of dilution of polyvitamin preparations
aquariums of such "ordinary" fish as goldfish, bothin electrochemically purified water ORP of
with and without UV Sterilizers (keep in mind thatmixtures is decreased approximately by 200 -
some UVs are useless by design and installation),400 mV in relation to the control solutions with
and the goldfish with every other factor equalnon-treated drinking water.
that had a UV Sterilizer installed, were generallyThis partially explains how a proper Redox
much healthier.Potential improves the health of the fish or other
Over geologic time abiogenic (not biological inaquatic organisms as I have observed. Bringing
origin), biogenic (produced by living organisms) andthis back to my observations of goldfish
anthropogenic (processes are those that areaquariums; All aquariums with the same filtration
derived from human activities, as opposed to(canister filter with sponge filter), the same
effects or processes that occur in the naturalfeeding schedule and food, even the same basic
environment without human influences) depositsgoldfish (a mix of ryukins and orandas); The
were accumulated in rivers, lakes and seas.aquariums with the quality, properly installed UV
Simultaneously there proceeded theSterilizers not only had less incidence of disease,
self-purification of natural water on the basis ofbut general health, appetite, vigor, growth, and
the chemical reactions of oxidation and reduction.water clarity were all improved.
Living organisms such as fish are adapted not toA few aspects of aquarium or pond husbandry
"perfectly clean water", such as distillated water,that will help maintain a balanced Redox:
but to ecologically clean water with definite(1) Regular and effective water changes (for both
content of organic and inorganic compounds,sides of the Redox equation)
micro-admixtures, ions and even bacteria or(2) IMPORTANT: Proper AND ONGOING
saprophyte (any plant that depends on dead plantmineralization, especially of calcium and magnesium
or animal tissue for a source of nutrition andcations (that is calcium & magnesium that
metabolic energy, e.g., most fungi). The range ofhas not been reduced and is positively charged).
mentioned components of ecologically clean water(3) UV Sterilization (even correct lighting)
is the integral result of oxidation and reduction(4) Good de-nitrification, plant filtration.
self-purification of water.(4) Keeping the production of nitric acid to a
At the initial stages of this cycle toxic hydrophobicminimum and balancing this out with adequate KH
organic compounds (molecules that are repelledlevels.